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<p class="MsoNormal" style="text-align:center;line-height:150%" align="center"><strong><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman";
mso-font-kerning:0pt">张海娇教授课题组在低维能源纳米材料方面取得新进展</span></strong><strong><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt" lang="EN-US"></span></strong></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif;mso-font-kerning:0pt" lang="EN-US"> </span></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;font-family:
宋体;mso-ascii-font-family:" times new roman";mso-fareast-font-family:宋体;
mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">近日，环化学院张海娇教授课题组在能源纳米材料领域的国际高水平期刊《</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt" lang="EN-US">Nano Energy</span><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:
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mso-font-kerning:0pt" lang="EN-US">15.548</span><span style="font-size:12.0pt;line-height:
150%;font-family:宋体;mso-ascii-font-family:" times new roman";mso-fareast-font-family:
宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">）上发表题为《</span><a name="OLE_LINK214"><span style="font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif" lang="EN-US">Three-dimensional<span class="fontstyle01"><span style="mso-ansi-font-size:12.0pt;mso-bidi-font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif;color:windowtext"> MoS<sub>2</sub>/carbon sandwiched architecture for boosted lithium storage capability</span></span></span></a><span style="mso-bookmark:OLE_LINK214"></span><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:
"times new roman";mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">》的研究论文，硕士生吴程昊为第一作者，张海娇教授为通讯作者，上海大学为第一通讯作者单位。</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;
font-family:" times new roman",serif;mso-font-kerning:0pt;mso-bidi-font-weight:
bold" lang="EN-US"> </span></p>
<p class="MsoNormal" style="text-align:center;line-height:150%" align="center"><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-font-kerning:0pt;mso-no-proof:yes" lang="EN-US"><img src="../../Portals/717/1(43).jpg" alt="" width="600" height="524" /></span><span style="font-size:12.0pt;
line-height:150%;font-family:" times new roman",serif;mso-font-kerning:0pt" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-indent:25.6pt;mso-char-indent-count:2.0;
line-height:150%"><span style="font-size:12.0pt;line-height:150%;font-family:
宋体;mso-ascii-font-family:" times new roman";mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";letter-spacing:.4pt;background:white">随着能源短缺和环境问题等的日益显著，锂离子电池成为主要的能量存储器件。</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman"">二硫化钼层状材料<span style="mso-no-proof:yes">在高能量密度锂电池中具有重要的研究意义，但该类材料普遍导电性差且存在较大的体积膨胀效应，从而导致电极结构的不稳定和循环寿命的快速衰减。虽然传统意义上的单层</span><span style="background:white">碳包覆可提高</span>电极材料的电导性和结构稳定性<span style="background:
white">，但裸露的那部分，仍然是不理想的。</span><span style="mso-no-proof:yes">针对以上关键问题，</span><span style="mso-font-kerning:0pt">张海娇教授课题组<span style="mso-no-proof:yes">通过</span>合理的实验设计和优化，在聚吡咯衍生的碳纳米管上生长二硫化钼纳米片的同时，成功实现了外层碳的均匀连续包覆，从而可获得电化学性能优异的氮掺杂的二硫化钼</span></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif" lang="EN-US">/</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman"">碳三明治型复合纳米材料</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-hansi-font-family:"times new roman";mso-bidi-font-family:
"times new roman";letter-spacing:.4pt;background:white">（</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-fareast-font-family:宋体;letter-spacing:.4pt;background:white" lang="EN-US">PCN@MoS<sub>2</sub>@C</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-hansi-font-family:"times new roman";mso-bidi-font-family:
"times new roman";letter-spacing:.4pt;background:white">）</span><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman"">。该中空管状结构可有效地缓冲锂离子脱嵌过程中导致的体积膨胀；更重要的是，<span style="color:black;mso-themecolor:text1">具有扩大层间距（</span></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
color:black;mso-themecolor:text1" lang="EN-US">0.98 nm</span><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:
"times new roman";mso-bidi-font-family:"times new roman";color:black;
mso-themecolor:text1">）的超薄</span><span style="font-size:12.0pt;
line-height:150%;font-family:" times new roman",serif;color:black;mso-themecolor:
text1" lang="EN-US">MoS<sub>2</sub></span><span style="font-size:12.0pt;line-height:150%;
font-family:宋体;mso-ascii-font-family:" times new roman";mso-fareast-font-family:
宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:"times new roman";
mso-bidi-font-family:"times new roman";color:black;mso-themecolor:text1">纳米片被限域在两个不同的导电碳层之间，提高离子传输和电导的同时，也稳定了电极的结构。实验结果和密度泛函理论计算表明，这种独特三明治型新颖结构的构筑，有效提升了锂离子在多次充放电过程的反应动力学，从而获得了优异的储锂性能。</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
color:black;mso-themecolor:text1" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-indent:24.0pt;mso-char-indent-count:2.0;
line-height:150%;tab-stops:28.0pt 56.0pt 84.0pt 112.0pt 140.0pt 168.0pt 196.0pt 224.0pt 252.0pt 280.0pt 308.0pt 336.0pt;
mso-layout-grid-align:none;text-autospace:none"><span style="font-size:12.0pt;
line-height:150%;font-family:宋体;mso-ascii-font-family:" times new roman";
mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:
"times new roman";mso-bidi-font-family:"times new roman";mso-font-kerning:0pt">该工作由上海大学、澳大利亚皇家墨尔本理工大学和东华大学共同合作完成，得到了国家自然科学基金委、上海市教委和科委等的资助和支持。</span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif" lang="EN-US"></span></p>
<p class="MsoNormal" style="text-align:left;text-indent:24.0pt;
mso-char-indent-count:2.0;line-height:150%;mso-pagination:widow-orphan" align="left"><span style="font-size:12.0pt;line-height:150%;font-family:宋体;mso-ascii-font-family:
" times new roman";mso-fareast-font-family:宋体;mso-fareast-theme-font:minor-fareast;
mso-hansi-font-family:"times new roman";mso-bidi-font-family:"times new roman";
color:black;mso-themecolor:text1;mso-font-kerning:0pt">论文链接：</span><span lang="EN-US"><a href="https://doi.org/10.1016/j.nanoen.2019.104061" target="_blank" title="Persistent link using digital object identifier"><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif">https://doi.org/10.1016/j.nanoen.2019.104061</span></a></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman",serif;
mso-fareast-font-family:"times new roman";color:blue;mso-font-kerning:0pt" lang="EN-US"></span></p>
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<span lang="EN-US"><a href="https://doi.org/10.1016/j.nanoen.2019.104061" target="_blank" title="Persistent link using digital object identifier"><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman","serif""></span></a></span><span style="font-size:12.0pt;line-height:150%;font-family:" times new roman","serif";
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